5212448 NMR pulse sequence with burst RF excitation pulses having separately controlled phase

Determination of the quadrupolar couplin

Determination of the quadrupolar coupling constant in powdered samples with a two in-phase rf pulse sequence in solid-state NMR

✍ Pascal P. Man 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 393 KB

We propose a new method for the determination of the quadrupolar coupling constant e'qQ/h of a spin I= 3/2 in powdered samples. It is suitable for characterizing a nucleus with a featureless central transition line shape where it is difkult to extract the value of e\*qQ/h from the spectrum. The puls