51V NMR of the layered δ-LiV2O5
✍ Scribed by Monisha Bose; Anjali Basu
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 353 KB
- Volume
- 81
- Category
- Article
- ISSN
- 0022-4596
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Single crystals of hydrated vanadium oxides with layered structures containing divalent Ca or Ni were hydrothermally grown, and their structural characterization was focused on the interlayer sites. Both compounds are formulated by M 0.25 V 2 O 5 • H 2 O, M ؍ Ca, Ni and crystallize in the monoclin
LiV 2 O 5 crystallize in the orthorhombic system, with Cmcm and Pmmn space groups, respectively. Transformation of into is initiated at about approximately 1103C. In both structures, lithium atoms are intercalated between [V 2 O 5 ] n layers built up by VO 5 square pyramids sharing edges and corners