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51V NMR and EPR study of the mechanistic details of oxidation with VO(O2) (Pic) (H2O)2

✍ Scribed by E.P. Talsi; K.V. Shalyaev

Publisher
Elsevier Science
Year
1994
Weight
675 KB
Volume
92
Category
Article
ISSN
0304-5102

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✍ Hauke Schmidt; IngegΓ€rd Andersson; Dieter Rehder; Lage Pettersson πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 268 KB

The speciation in the quaternary aqueous H /H 2 VO 4 Γ€ /H 2 O 2 /l-aalanyl-l-histidine (Ah) system has been determined from quantitative 51 V NMR measurements and potentiometric data (glass electrode). The study was performed in 0.150 m Na(Cl) medium at 25 8C. Data were evaluated with the computer p