51V chemical shift and 51V-31P coupling in carbonyl complexes of vanadium
β Scribed by Dieter Rehder
- Publisher
- Elsevier Science
- Year
- 1977
- Weight
- 353 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0022-2364
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π SIMILAR VOLUMES
Quadruple coupling and chemical shift anisotropy are of comparable magnitudes in the NMR of quadrupole nuclei of heavy atoms. Magic angle spinning (MAS) and off-MAS NMR spectra of 'lV and 59C0 nuclei were measured for vanadium(V)aitrilotriacetate complex, cobalt(0) acetylacetonate and ammonium metav
The "V-NMR spectroscopic behavior in water of a series of vanadium peroxo complexes was investigated. Monoperoxo vanadium complexes containing bidentate ligands in which the two binding sites are either oxygen atoms (0 f~ 0 ligands) or one oxygen and one nitrogen atom (N n 0 ligands) and diperoxo va
Static and magic angle spinning 51V NMR spectra of were recorded at three di β erent Γeld BiVO 4 strengths (2.3, 9.4 and 14.1 T) and give evidence of the relative e β ects of the quadrupolar interaction and electronic shielding at the nucleus. The experimental powder spectra were Γtted to ascertain bo