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[5,10,15,20-Tetrakis(2,6-dimethoxyphenyl)porphyrinato]nickel(II)–toluene–dichloromethane (3/2/4):a mixed solvate

✍ Scribed by Conrad, Diane ;DeCoskey, Jennifer ;Yeisley, Christopher ;Zeller, Matthias ;Hunter, Allen D. ;Zovinka, Edward P.

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 778 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807051872

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✦ Synopsis

The crystal structure, electronic spectroscopy, and ^1^H NMR data for the title compound, [Ni(C~52~H~44~N~4~O~8~)]·0.67C~7~H~8~·1.33CH~2~Cl~2~, are reported. The compound was prepared by the reaction of nickel(II) acetate with the ligand in refluxing glacial acetic acid. The asymmetric unit consists of 1.5 nickel porphyrins, two dichloromethane molecules and one toluene molecule. One of the nickel–porphyrinate molecules is located on an inversion center and is planar in the solid state, while the other assumes a saddle-shaped geometry. In both cases, the nickel ion is four-coordinate.

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✍ Kojima, Takahiko ;Harada, Ryosuke 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 152 KB

The structure of the title compound, [Zn(C 92 H 60 N 4 )-(C 2 H 3 N)]ÁC 2 H 3 N, shows relatively small saddle-type distortion with ruf¯ing, compared to other dodecaphenylporphyrin complexes.