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5,10,15,20-Tetra-(N-methyl-3-pyridyl)porphyrin destabilizes the antiparallel telomeric quadruplex d(TTAGGG)4

✍ Scribed by Yu. V. Dutikova; O. F. Borisova; A. K. Shchyolkina; J. Lin; S. Huang; A. A. Shtil; D. N. Kaluzhny

Book ID
110174860
Publisher
SP MAIK Nauka/Interperiodica
Year
2010
Tongue
English
Weight
316 KB
Volume
44
Category
Article
ISSN
0026-8933

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Kinetic simulation studies on the transient formation of the oxo-iron(IV) porphyrin radical cation during the reaction of iron(III) tetrakis-5,10,15,20-(N-methyl-4-pyridyl)-porphyrin with hydrogen peroxide in aqueous solution
✍ Tapan Kumar Saha; Subarna Karmaker; Keietsu Tamagake πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 279 KB πŸ‘ 3 views

High-valent oxo-iron(IV) species are commonly proposed as the key intermediates in the catalytic mechanisms of iron enzymes. Water-soluble iron(III) tetrakis-5,10,15,20-(N-methyl-4-pyridyl)porphyrin (Fe(III)TMPyP) has been used as a model of heme-enzyme to catalyse the hydrogen peroxide (H 2 O 2 ) o