In memory of Prof. D.H
5,10-seco-steroids, a new type of steroid derivatives containing a ten-membered ring
✍ Scribed by M.Lj. Mihailović; M. Stefanović; Lj. Lorenc; M. Gašić
- Publisher
- Elsevier Science
- Year
- 1964
- Tongue
- French
- Weight
- 183 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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5,lO-Seco-steroida containing a ten-membered ring (2) (instead of the two fused six-membered rings A and B) (e.g. I and II on Scheme 1) represent a suitable eubetrate for the study of truuunmilar reactivity in a medim-aired ring sytatem, because of the rel&ive rigidity of the general steroid framewo
## Thermal decomposition of steroidal 5q,8a-peroxides (such as
Dedicated to Dr. Gunther OhlofTon the occasion of his 65th birthday (7.11.89) Thermolysis of steroidal 5~,8a~peroxides of type 3a-d generates as major products the corresponding diseco compounds containing a 14-membered ring instead of the standard A-B-C-ring skeleton. Depending on the reaction cond