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51 V NMR Chemical Shifts Calculated from QM/MM Models of Peroxo Forms of Vanadium Haloperoxidases

✍ Scribed by Geethalakshmi, K. R.; Waller, Mark P.; Thiel, Walter; Bühl, Michael

Book ID
127334084
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
550 KB
Volume
113
Category
Article
ISSN
0022-3654

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The "V-NMR spectroscopic behavior in water of a series of vanadium peroxo complexes was investigated. Monoperoxo vanadium complexes containing bidentate ligands in which the two binding sites are either oxygen atoms (0 f~ 0 ligands) or one oxygen and one nitrogen atom (N n 0 ligands) and diperoxo va