5-endo-(Bromomethyl)-1,2,4-trichloro-3,7,7-trimethoxynorborn-2-ene
โ Scribed by Van Hemelrijk, D. ;Lenstra, A. T. H. ;Geise, H. J.
- Book ID
- 114528843
- Publisher
- International Union of Crystallography
- Year
- 1982
- Weight
- 447 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0567-7408
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## Abstract Hydrolysis of 6โ(bromomethyl)โ 1,2,4โtrichloroโ3,7,7โtrimethoxybicyclo[2.2.1] heptโ2โene with perchloric acid in aqueous ethanol yields inter __alia__ the title compound. Xโray analysis proved the positioning of the substituents to be 6โ__endo__โ(bromomethyl)โ2โ__endo__โchloro,3โ__endo_
In the title compound, C 16 H 13 Cl 3 N 2 O 3 S, the 1,3-thiazole ring is almost orthogonal to the isoindoline plane, making a dihedral angle of 89.74 (9) . Intermolecular O-Hร ร รN and C-Hร ร รO interactions and Sร ร รO short contacts link the molecules into a three-dimensional framework. The cryst