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5-Chloro-3-methylthio-1,2,4-thiadiazol-2-ium Chlorides as Useful Synthetic Precursors to a Variety of 6aλ4-Thiapentalene Systems.

✍ Scribed by Georges Morel; Evelyne Marchand; Sourisak Sinbandhit; Loic Toupet


Publisher
John Wiley and Sons
Year
2003
Weight
201 KB
Volume
34
Category
Article
ISSN
0931-7597

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5-Chloro-3-methylthio-1,2,4-thiadiazol-2
✍ Georges Morel; Evelyne Marchand; Sourisak Sinbandhit; Loic Toupet 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 171 KB

## Abstract Title salts **3** were easily obtained by treatment of formimidoyl isothiocyanates **1** with a twofold excess of methanesulfenyl chloride. They showed interesting chemical behavior toward several nitrogen and carbon nucleophiles. Substitution reactions with isothioureas and acetamide i