5-Benzyl-8-(E)-benzylidene-6,7,7a,10a-tetrahydro-5H-cis-cyclopenta[5,6]pyrano[3,3-c]quinolin-6-one
✍ Scribed by Aravindan, S. ;Sampath, N. ;Ponnuswamy, M. N. ;Kalaivasan, N. ;Raghunathan, R. ;Nethaji, M.
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 316 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 29 H 23 NO 2 , the quinolinone moiety is planar and the pyran ring is in a half-chair form. The cyclopentene fused with the pyran ring adopts an envelope conformation. There are CÐHÁ Á ÁO, CÐHÁ Á Á% and %Á Á Á% intermolecular interactions.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 143 K Mean '(C±C) = 0.004 A Ê R factor = 0.054 wR factor = 0.146 Data-to-parameter ratio = 12.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C~18~H~17~NO~2~, synthesized from enantiomerically pure L-proline, methyl chloroformate and a Grignard reagent, crystallizes with two molecules in the asymmetric unit. A chair conformation is adopted by the two fused five-membered rings.