(4R,5R)-2-(N-Methyl-benzylamino)-3-nitro-4-(1′,2′,3′,4′,5′-penta-O-acetyl-d-manno-pentitol-1-yl)-5-phenyl-5-phenylcarbamoyl-4,5-dihydrothiophene at 150 K
✍ Scribed by Diánez, María Jesús ;Estrada, María Dolores ;López-Castro, Amparo ;Pérez-Garrido, Simeón
- Publisher
- International Union of Crystallography
- Year
- 2001
- Tongue
- English
- Weight
- 183 KB
- Volume
- 57
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
A Z arrangement of substituents about the carboxylate C-O bond causes a syn positioning of the carbonyl O atom and the heterocyclic part of the title compound, C 18 H 15 NO 3 S. The carboxylate entity is inclined by À28.1 (3) to the phenyl group. The planes of the thiazol-2(3H)-thione subunit and th
The title hept-I -enitol( 2) reacted with aldehyde methyl(or phenyl)hydrazones in refluxing methanol or butyl acetate to give I-methyl(or phenyl)-5-(penta-O-acetyl-~-~~u~u~f~~-pentitol-l-yl)pyrazoles in good (for I-methylpyrazoles) or moderate yields (for I-phenylpyrazolcs). The 0-deacetylated produ
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.045 wR factor = 0.126 Data-to-parameter ratio = 12.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Synthesis and absolute configuration of methyl