𝔖 Bobbio Scriptorium
✦   LIBER   ✦

47/49Ti NMR of some titanium compounds

✍ Scribed by S. Berger; W. Bock; C. F. Marth; B. Raguse; M. T. Reetz


Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
187 KB
Volume
28
Category
Article
ISSN
0749-1581

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

The results of ^47/49^Ti NMR measurements on 21 organotitanium compounds are reported. A signal could be detected for only about half of the compounds measured. Methyltitanium trichloride is highly deshielded compared with TiCl~4~.


📜 SIMILAR VOLUMES


47, 49Ti NMR spectra of half-sandwich ti
✍ Milan Erben; Aleš Růžička; Michal Picka; Ivan Pavlík 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 90 KB

## Abstract The ^47, 49^Ti chemical shifts, resonance line half‐widths (Δν~1/2~) and energies of the first electronic charge‐transfer transitions $(\lambda\_{\max}^{\rm 1.CT})$ of Cp′TiX~3~, where Cp′ = η^5^‐C~5~H~5~ (Cp), η^5^‐C~5~H~4~Me (MeCp), η^5^‐C~5~HMe~4~ (Me~4~Cp), η^5^‐C~5~Me~5~ (Me~5~Cp),

Density functional computation of 49Ti N
✍ Michael Bühl; Frank T. Mauschick 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 165 KB

## Abstract ^49^Ti chemical shifts of TiX~4~ (X = Cl, Br, F), TiCl~__n__~Me~(4−__n__)~ (__n__ = 0–3), Ti(C~5~H~5~)~2~X~2~ (X = F, Cl, Br) and Ti(CO)~6~^2−^ were computed, using geometries optimized with the gradient‐corrected BP86 density functional, at the GIAO (gauge‐including atomic orbitals)–Ha