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4,6-O-benzylidene-1,2-dideoxy-d-erythro-hex-1-enopyran-3-ulose

✍ Scribed by P.M. Collins

Book ID
108307683
Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
271 KB
Volume
11
Category
Article
ISSN
0008-6215

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Benzotriazol-1-yl 4,6-di-O-acetyl-2,3-di
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✍ Low, John Nicolson ;Cobo, Justo ;LΓ³pez, M. Dolores ;Nogueras, Manuel ;SΓ‘nchez, A πŸ“‚ Article πŸ“… 2003 πŸ› International Union of Crystallography 🌐 English βš– 298 KB

In the title compound {systematic name: [3(S)-acetyloxy-6(S)-(1H-1,2,3-benzotriazol-1-yl)-3,6-dihydro-2H-pyran-2(S)-yl]methyl acetate}, C 16 H 17 N 3 O 5 , weak CÐHÁ Á ÁO hydrogen bonds link the molecules to form a three-dimensional network consisting of linked helical chains.

Preparation, and nucleophilic addition-r
Preparation, and nucleophilic addition-reactions, of 1,5- anhydro-4,6-O-benzylidene-2,3-dideoxy-2-nitro-d-erythro-hex-2-enitol
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## Nucleophilic addition-reactions of the title compound, prepared from the corresponding 3-nitrohex-2-enitol, were investigated under kinetically controlled conditions; such sterically bulky nucleophiles as tert-butyl peroxide and 2,4-pentanedionate ions (except in 1,Cdioxane) were found to enga