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4.6-dimethyl-7-hydroxy-nonan-3-one, a sex pheromone of the cigarette beetle (Lasioderma serricorne F.)

✍ Scribed by Tatsuji Chuman; Masahiro Kohno; Kunio Kato; Masao Noguchi


Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
198 KB
Volume
20
Category
Article
ISSN
0040-4039

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✦ Synopsis


A structure of the sex pheromone produced by the female cigarette beetle (Lasioderma serricorne F.) is established as 4,6-dimethyl-7-hydroxy-nonan-3-one (Ia) by chemical and spectroscopic evidences.


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Determination of the absolute configurat
✍ Kenji Mori; Hiroko Nomi (nΓ©e Iwasawa); Tatsuji Chuman; Masahiro Kohno; Kunio Kat πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 228 KB

The absolute configuration at C-6 and C-7 of serricornin was established as (6S, 75) by synthesizing its (65, 7S)-erythro and (6R, 7R)threo isomers.