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4,6-Dimethoxy-2-(methylsulfanyl)-5-phenylpyrimidine

✍ Scribed by Huang, Tong-Hui ;Zhao, Na ;Chen, Li-Fang ;Cheng, Hong-Gang ;Luo, Fei-Hua

Book ID
104491273
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
852 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the asymmetric unit of the title structure, C 13 H 14 N 2 O 2 S, there are two independent molecules. All bond lengths and angles show normal values. The dihedral angles between the phenyl and pyrimidine rings in each molecule are 58.66 (9) and 57.88 ( 8) , but these rings are rotated in opposite directions with respect to the S-C bond of the methylsulfanyl substituent. In the absence of hydrogen bonds, the crystal structure is stabilized by van der Waals forces and one weak C-HÁ Á Á(arene) interaction, with HÁ Á ÁCg = 2.91 A ˚(Cg is the centroid of the pyrimidine ring).

Related literature

Pyrimidine derivatives have been studied because of their biological properties (see

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