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4,6-Bis{2′-hydr­oxy-2′,3′-dihydro­spiro­[cyclo­propane-1,1′(1H)-inden]-3′-­yl}isophthalonitrile

✍ Scribed by Lu, Zhi-Feng ;Xu, Jian-Hua ;Teh, Jeannie Bee-Jan ;Fun, Hoong-Kun


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
313 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, C~30~H~24~N~2~O~2~, the central benzene ring forms dihedral angles of 84.3 (1) and 86.4 (1)° with the terminal benzene rings. The crystal structure is stabilized by O—H...O and C—H...π interactions.


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In the crystal structure of the title compound, C~15~H~12~Cl~2~O~2~, the chloro-substituted benzene rings are not parallel; the other rings are nearly parallel and the molecules stack in layers parallel to these rings. There are two molecules in the asymmetric unit.

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## Abstract ^1^H, ^13^C and two‐dimensional NMR analyses were applied to determine the NMR parameters of 6‐(2′,3′‐dihydro‐1′__H__‐inden‐1′‐yl)‐1__H__‐indene. The measurements were accomplished with 0.5 mg of the substance, this quantity being sufficient to determine the chemical shifts of all the H