In this study, (5a,7a)-4,5-epoxy-3,6-dimethoxy-17-methyl-6,14-ethenomorphinan-7-carboxylic acid hydrazide (5) was synthesized by the condensation of methyl (5a,7a)-4,5-epoxy-3,6-dimethoxy-17methyl-6,14-ethenomorphinan-7-carboxylate (4) with NH 2 NH 2 • H 2 O. The (5a,7a)-4,5-epoxy-3,6-dimethoxy-17-m
✦ LIBER ✦
4,5-Dimethoxyphthalimide and 6,7-dimethoxy-2,3-naphthalimide — Two new chromophoric derivatives for the amino group
✍ Scribed by Jacek Gawroński; Krystyna Gawrońska; Małgorzata Brzostowska
- Book ID
- 104260538
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 200 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
We have developed new chromophoric derivatives for the amino group: 4,5-dimethoxyphthalimide and 6,7-dimethoxy-2,3-naphthalimide, particularly suitable for CD applications. These highly fluorescent imides show very strong Cotton effects due to exciton coupling which are red-shifted with respect to the parent phthalimide and 2,3-naphthalimide chromophores. No significant Cotton effects other than those due to the transition with the electric dipole transition moment colinear with the C2-axis of the chromophore were observed.
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