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4,5-Dichloro-1,2,3-dithiazolium chloride (Appel's Salt): Reactions with N-nucleophiles.

✍ Scribed by Ana M. Cuadro; Julio Alvarez-Buila


Book ID
118549821
Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
614 KB
Volume
50
Category
Article
ISSN
0040-4020

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Reactions of 3,5-Diaryl-1,2-dithiolium S
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## Abstract Reaction of the 3,5‐diaryl‐1,2‐dithiolium salts 2 with the metal cyclopentadienides 4 and 9 leads to the formation of the tricyclic compounds 6 and 10 via a ring‐opened intermediate, which undergoes an intramolecular Diels‐Alder cyclization. Compounds 6 and 10 rearrange by treatment wit