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4,5-Bis(dimethylamino)quinolines: Proton Sponge versus Azine Behavior

✍ Scribed by Dyablo, Olga V.; Shmoilova, Elena A.; Pozharskii, Alexander F.; Ozeryanskii, Valery A.; Burov, Oleg N.; Starikova, Zoya A.


Book ID
118007225
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
958 KB
Volume
14
Category
Article
ISSN
1523-7060

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Low-temperature (120 K) studies of the structure of the DMAN Á DCI adduct indicate that in symmetrical [NHN] hydrogen bridge of 2.571 (1) A ˚length (2.579(2) A ˚at room temperature) there is a disorder of the H-atom occupying two positions at nitrogen atoms with a distance of 0.94(3) A ˚. The compa