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4,4′-Bipiperidinediium bis(hydrogen chloranilate)

✍ Scribed by Gotoh, Kazuma ;Ishikawa, Rie ;Ishida, Hiroyuki


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
503 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the crystal structure of the title 1:2 salt, C 10 H 22 N 2 2+ Á-2C 6 HCl 2 O 4 À , the 4,4 0 -bipiperidinium dication and the two hydrogen chloranilate anions are held together by N-HÁ Á ÁO and C-HÁ Á ÁO hydrogen bonds. Two 1:2 units are connected by O-HÁ Á ÁO hydrogen bonds, forming a centrosymmetric molecular ring. The rings are further linked by O-HÁ Á ÁO, N-HÁ Á ÁO and C-HÁ Á ÁO hydrogen bonds, leading to a threedimensional hydrogen-bonding network. Related literature For related literature, see: Allen (2002); Ishida (2004); Refat et al. (2006).


📜 SIMILAR VOLUMES


1,4-Phenyl­enediammonium bis­(hydrogen p
✍ Wang, Kui-Wu ;Zhang, Hong ;Shen, Lian-Qing 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 125 KB

The title compound, C 6 H 10 N 2 2+ Á2C 8 H 5 O 4 ## À , is a protontransfer compound obtained from 1,4-phenylenediamine and phthalic acid. The asymmetric unit contains half of a centrosymmetric cation and an anion. A strong intramolecular O-HÁ Á ÁO hydrogen bond is found in the anion. The cation