4,4′-Bipiperidinediium bis(hydrogen chloranilate)
✍ Scribed by Gotoh, Kazuma ;Ishikawa, Rie ;Ishida, Hiroyuki
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 503 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the crystal structure of the title 1:2 salt, C 10 H 22 N 2 2+ Á-2C 6 HCl 2 O 4 À , the 4,4 0 -bipiperidinium dication and the two hydrogen chloranilate anions are held together by N-HÁ Á ÁO and C-HÁ Á ÁO hydrogen bonds. Two 1:2 units are connected by O-HÁ Á ÁO hydrogen bonds, forming a centrosymmetric molecular ring. The rings are further linked by O-HÁ Á ÁO, N-HÁ Á ÁO and C-HÁ Á ÁO hydrogen bonds, leading to a threedimensional hydrogen-bonding network. Related literature For related literature, see: Allen (2002); Ishida (2004); Refat et al. (2006).
📜 SIMILAR VOLUMES
The title compound, C 6 H 10 N 2 2+ Á2C 8 H 5 O 4 ## À , is a protontransfer compound obtained from 1,4-phenylenediamine and phthalic acid. The asymmetric unit contains half of a centrosymmetric cation and an anion. A strong intramolecular O-HÁ Á ÁO hydrogen bond is found in the anion. The cation