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4,10a-(Epidithio)-4,4a,10,10a-tetrahydro-1H-5-oxaanthracen-1-ones, tetracycles with a novel heterocyclic ring system

✍ Scribed by Sandra Kolly; Hansrudolf Meier; Grety Rihs; Tammo Winkler


Book ID
102258702
Publisher
John Wiley and Sons
Year
1988
Tongue
German
Weight
388 KB
Volume
71
Category
Article
ISSN
0018-019X

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✦ Synopsis


The 4,4',6,6'-tetrasubstituted 2,2'-alkylidene-bisphenols 1 reacted with sulfur monochloride to give 4, IOa-(epi-dithi0)-4,4a,lO, 1Oa-tetrahydro-lH-5-oxaanthracen-I-ones (3 and 4). The structures of the products were elucidated by a combination of X-ray crystal-structure analysis and 'Hand "C-NMR spectroscopy.


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## Abstract The title novel fused tricyclic phosphoroheterocycle, C~19~H~20~N~3~O~2~PS, was synthesized in an excellent yield of 88.5% via the reac‐ tion of 1‐(2‐bromoethyl)‐2,3‐dihydro‐3‐propyl‐1,3,2‐benzodiazaphosphorin‐4(1__H__)‐one 2‐oxide with phenyl isothiocyanate, which contains the proximat