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4-Methyl-2,5-(cis)-7-nonatriene, a new linear dimer of trans-piperylene

✍ Scribed by G. A. Tolstikov; G. E. Ivanov; V. P. Yur'ev


Book ID
112437840
Publisher
Springer
Year
1974
Tongue
English
Weight
97 KB
Volume
23
Category
Article
ISSN
1573-9171

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Nitro Ketones in Organic Synthesis: A Ne
✍ Ballini, Roberto ;Bosica, Giovanna ;Schaafstra, Robert πŸ“‚ Article πŸ“… 1994 πŸ› John Wiley and Sons 🌐 English βš– 235 KB

## Abstract The synthesis of spiroketals from nitro ketones is described. Racemic __trans__‐2‐Methyl‐1,7‐dioxaspiro[5.5]undecane (1a), and 2,8‐dimethyl‐1,7‐dioxaspiro[5.5]undecane (1b) are synthesized as a mixture of __trans__, __trans__ and __trans__, __cis__ isomers in a ratio of 6.5:3.5 (separab