4-Hydroxy-3-[( E )-3-phenylprop-2-enoyl]-2 H -chromen-2-one
✍ Scribed by Ghouili, Afef; Ben Hassen, Rached
- Book ID
- 125511952
- Publisher
- International Union of Crystallography
- Year
- 2011
- Tongue
- English
- Weight
- 383 KB
- Volume
- 67
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The geometric parameters of the title molecule, C~27~H~25~NO~4~, are in the usual ranges. The central C=C double bond is __trans__ configured, with the two C atoms slightly twisted out of the plane of the naphthyl group. The dihedral angle between the two fused ring systems is 40.90 (4)°.
The herbicide 3-phenyl-1-(2-hydroxy-3-iodo-4,6-dimethoxyphenyl)propen-1-one, C 17 H 15 IO 4 , exists as a nearly planar molecule; the hydroxy group forms an intramolecular hydrogen bond with the carbonyl O atom.
## Abstract 3‐Acetyl‐4‐hydroxy‐chromen‐2‐one (**1**) was brominated with phenyltrimethylammonium tribromide to afford 3‐(2‐bromoacetyl)‐4‐hydroxy‐chromen‐2‐one (**2**) whose reactions with thiourea, thioacetamide and ammonium dithiocarbamate gave respectively 3‐(2‐amino‐thiazol‐4‐yl)‐4‐hydroxy‐, 4‐