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4′-Functionalized 2,2′:6′,2″-terpyridines as building blocks for supramolecular chemistry and nanoscience

✍ Scribed by Ulrich S Schubert; Christian Eschbaumer; Oliver Hien; Philip R Andres

Book ID
104230861
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
98 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

Different mono-and bis-terpyridines were synthesized utilizing nucleophilic substitution of 4%-chloro-2,2%:6%,2¦-terpyridine. In the case of the mono-functionalized ligands, different functional groups opposite to the metal binding site could be introduced; with the bis-functionalized ligands building blocks for metal-containing polymers with a tailored alkyl-chain length were accessible. As examples, a functionalized terpyridine cadmium(II) complex as well as a fullerene derivative were prepared.

📜 SIMILAR VOLUMES

New 4′-Functionalized 2,2′:6′,2′′-Terpyr
New 4′-Functionalized 2,2′:6′,2′′-Terpyridines for Applications in Macromolecular Chemistry and Nanoscience
✍ Philip R. Andres; Ralph Lunkwitz; Gunther R. Pabst; Karlheinz Böhn; Daan Wouters 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 310 KB 👁 1 views

## Abstract The well‐known reaction of 4′‐chloro‐2,2′:6′,2′′‐terpyridine with alkoxide nucleophiles leads to 4′‐functionalized 2,2′:6′,2′′‐terpyridines. This reaction allows the easy introduction of different functional groups onto the terpyridine at the 4′‐position, i.e. opposite to the metal bind