## Abstract Three novel iniferter reagents were synthesized and used as initiators for the polymerizations of methyl methacrylate (MMA) and styrene (St) in the presence of copper(I) bromide and __N,N,N__β²,__N__β³,__N__β³βpentamethyldiethylenetriamine at 90 and 115Β°C, respectively. All the polymerizat
4-[Diphenyl(trimethylsilyl)methyl]benzophenone as initiator in the photopolymerization of methyl methacrylate and styrene
β Scribed by Dimitrios A. Tasis; Michael G. Siskos; Antonios K. Zarkadis
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 546 KB
- Volume
- 199
- Category
- Article
- ISSN
- 1022-1352
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The Group 4 metallocene bis(enolate) complexes [Cp 2 M(-O-CMeCH 2 ) 2 ] (1) add one or two molar equivalents of the organometallic Lewis acid B(C 6 F 5 ) 3 to form the addition products (3), respectively. Complexes 3 a (M Ti) and 3 b (M Zr) were characterized by X-ray diffraction. Complexes 2 under