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4-dimethylaminopyridine: an efficient and selective catalyst for the silylation of alcohols

โœ Scribed by S.K. Chaudhary; O. Hernandez


Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
206 KB
Volume
20
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


The importance of the hydroxyl group functionality in synthetic organic chemistry is reflected by the continuous appearance in the literature of methods for developing complex structures based on the chemical interconversion of oxygenated functionalities.

A limiting factor in some cases is the presence of more than one oxygen function of comparable reactivity in the molecule to be transformed.


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Potassium permanganate supported on zeolite can be used for the selective oxidation of various enamines, alkylarenes and unsaturated alcohols to the corresponding ketones, in good yield. Arches were selectively oxidized at the benzylic position. If the benzylic carbon is secondary, ketones are obtai