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4-Bromo­phenyl 2,6-di­bromo­phenyl ether

✍ Scribed by Eriksson, Johan ;Eriksson, Lars ;Hu, Jiwei

Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
457 KB
Volume
58
Category
Article
ISSN
1600-5368

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2,4-Di­bromo­phenyl 2,6-di­bromo­phenyl
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✍ Eriksson, Johan ;Eriksson, Lars ;Hu, Jiwei 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 240 KB

The title compound, C 12 H 6 Br 4 O, is the fourth well characterized of a total of potentially 209 different brominated diphenyl ethers. Salient intermolecular interactions are between ether O and aromatic C atoms, and between a bromine substituent and the aromatic ring system.

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✍ Eriksson, Lars ;Hu, Jiwei 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 299 KB

The title compound, C 12 H 7 Br 3 O, belongs to a group of ¯ame retardants known as polybrominated diphenyl ethers (PBDE). Salient features of the packing of the title compound are in®nite intermolecular BrÁ Á ÁBr contact chains along the b direction.

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê R factor = 0.033 wR factor = 0.065 Data-to-parameter ratio = 16.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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✍ Eriksson, Lars ;Hu, Jiwei 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 322 KB

The title compound, C 12 H 4 Br 6 O, belongs to a group of ¯ame retardants known as polybrominated diphenyl ethers (PBDE). Intermolecular BrÁ Á ÁBr contacts in the bc plane give a sheetlike character to the structure of the title compound.

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2,3,4,5,6-Penta­bromo­phenyl phenyl ethe
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✍ Eriksson, Lars ;Hu, Jiwei 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 396 KB

The title compound, C 12 H 5 Br 5 O, belongs to a group of ¯ame retardants known as polybrominated diphenyl ethers (PBDE). Salient features of the packing are stabilization due to intermolecular BrÁ Á ÁBr contacts in the ab plane and aromatic intermolecular contacts along the c direction.