The title compound, C 12 H 17 N 3 O, was obtained by the direct solvent-free reaction of salicylaldehyde with 1-amino-4methylpiperazine. The piperazine ring adopts a chair conformation. In the crystal structure, strong intramolecular O-HÁ Á ÁN hydrogen bonds, weak intermolecular C-HÁ Á ÁO hydrogen b
4-{[1-(1-Adamantyl)ethyl]iminomethyl}phenol
✍ Scribed by Feng, Yun-Long ;Zhao, Guo-Liang ;Wen, Yi-Hang
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 203 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The crystal structure of the title compound, C 16 H 17 NO 2 , contains two independent molecules in the asymmetric unit. Both molecules adopt the phenol-imine tautomeric form, with strong intramolecular O-HÁ Á ÁN hydrogen bonds. The crystal packing is stabilized by van der Waals interactions.
The title compound, C 14 H 12 N 2 O 4 , exists as an enol-imine tautomer, in which a strong intramolecular O-HÁ Á ÁN hydrogen bond is formed. This study verifies the preference of the enol-imine tautomeric form in the solid state.
The title compound, [Fe(C 5 H 5 )(C 19 H 15 ClN)], a new ketiminecontaining ferrocenyl derivative, has been synthesized and characterized structurally. Conjugation between the two benzene rings and the imine group is not observed. In addition, there are no significant intermolecular interactions.