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(3S)-4-Phenyl-3-(phenylaminooxy)butan-2-one

✍ Scribed by Yang, Li ;Fang, Hua ;Zheng, Hu ;Weng, Ling-Ling

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
704 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C 16 H 17 NO 2 , is an intermediate in our work on chiral acyloins. The crystal structure shows that molecules are linked by N-HÁ Á ÁÁO hydrogen bonds.

Related literature

For related literature, see: Co ´rdova et al. (2004); Davis & Chen (1992); Hayashi et al. (2004); Momiyama et al. (2004). Experimental Crystal data C 16 H 17 NO 2 M r = 255.31 Orthorhombic, P2 1 2 1 2 1 a = 5.5950 (17) A b = 15.847 (5) A c = 16.156 (5) A ˚V = 1432.4 (7) A ˚3 Z = 4 Mo K radiation = 0.08 mm À1 T = 293 (2) K 0.48 Â 0.18 Â 0.09 mm Data collection Bruker APEX area-detector diffractometer Absorption correction: multi-scan (SADABS; Bruker, 2001) T min = 0.751, T max = 1.000 7191 measured reflections 1571 independent reflections 781 reflections with I > 2(I) R int = 0.148 Refinement R[F 2 > 2(F 2 )] = 0.055 wR(F 2 ) = 0.145 S = 0.85

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