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(3aS,4S,4aS,7R,9S,9aS)-Methyl 4-benzyloxy-9-methyl­sulfonyloxy-2,2-dimethyl-8-oxoocta­hydro-1,3-dioxa-5-thia-7a-azacyclopenta[f]azulene-7-carboxyl­ate toluene solvate

✍ Scribed by Hörger, Rolf ;Marsch, Michael ;Geyer, Armin ;Harms, Klaus

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
169 KB
Volume
61
Category
Article
ISSN
1600-5368

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The title compound, C 27 H 34 ClNO, was synthesized by a direct condensation reaction. The molecule has three chiral centres, which exhibit R, S and R absolute configurations, respectively. Two six-membered rings with different conformations coexist in the structure and they form a trans ring juncti