3a,4,9,9a-Tetrahydro-2-methyl-4β-phenylbenz[f]isoindoline
✍ Scribed by Murray-Rust, P. ;Murray-Rust, J. ;Middlemiss, D.
- Book ID
- 114527043
- Publisher
- International Union of Crystallography
- Year
- 1980
- Weight
- 299 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0567-7408
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📜 SIMILAR VOLUMES
The carbazole unit of the title molecule, C 15 H 15 NO 3 , is not planar. The dihedral angle between the benzene ring and the fused pyrrole ring is 0.9 (1) . The cyclohexene ring is in a halfchair form. The ester group has an equatorial orientation. In the crystal structure, the molecules are stabil
1998 structure structure (organic substances) K 9000 25 -047 4-Benzyl-2,9-bis (phenylsulfonyl)-1,2,3,4-tetrahydro-9H-β-carboline. -Benzo and pyrrolo ring of the title compound (I) are planar; the pyridino ring adopts half-chair conformation. The molecules are stabilized by weak inter-and intramolecu
The reaction of 4a-methyl-l,2,3,4-tetrahydrocarbazole (1) with organolithium reagents affords the sterically hindered alkyl, aryl or alkenyl cis-4a-methyl-9a-substituted-l,2,3,4,4a,9ahexahydrocarbazole derivatives (2) in excellent yields. Two diastereomeric pairs were isolated for the 9a-see-butyl d