38. XPS determination of charge distribution in alkali metal GIC's

✍ Scribed by S.B. Dicenzo; S. Basu; G.K. Wertheim; D.N.E. Buchanan

• Book ID: 103000111
• Publisher: Elsevier Science
• Year: 1982
• Tongue: English
• Weight: 127 KB
• Volume: 20
• Category: Article
• ISSN: 0008-6223
• DOI: 10.1016/0008-6223(82)90457-2

✦ Synopsis

We report the results of self-consistent band structure calculations for Li&, LiC,*, and LiCls in idealized crystal structures representing first, second, and third stage intercalation compounds. Results for LiC,* indicate that 90% of the net excess charge is localized in the region between the two graphite planes facing the Li ions. In contrast, only 40% of the conduction electron charge is localized in that region.