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376. Isothiazoles. Part II. Isothiazolealdehydes and isothiazolyl ketones

โœ Scribed by Buttimore, D. ;Jones, D. H. ;Slack, R. ;Wooldridge, K. R. H.

Book ID
119940852
Publisher
The Royal Society of Chemistry
Year
1963
Weight
812 KB
Category
Article
ISSN
0368-1769

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A new mild oxidation of amines to aldehy
A new mild oxidation of amines to aldehydes and ketones. Part II
โœ Huai Gu Chen; Paul Knochel ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 123 KB

## Summm: The silylamines 1, after conversion into their lithium or zinc salts, were readily oxidized by dry air under very mild conditions (-60' C to -20' C, 5-45 min.) into the corresponding aldehydes or ketones 2 in good yields. Our reaction conditions tolerate the presence of other oxidation s