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3,6-Di-tert-butyl-o-benzosemiquinone complexes of copper(1) with bidentate bis(diphenylphosphine) ligands. Synthesis, structures, and properties

✍ Scribed by G. A. Abakumov; V. K. Cherkasov; A. V. Krashilina; I. L. Eremenko; S. E. Nefedov

Publisher
Springer
Year
1998
Tongue
English
Weight
730 KB
Volume
47
Category
Article
ISSN
1573-9171

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The Reaction of 3,6-di-tert-butyl-o-benzoquinone with tin amalgam: Synthesis and structure of tin catecholato complexes
✍ Alexandr V. Piskunov; Aryna V. Lado; Georgy K. Fukin; Evgeny V. Baranov; Ludmila 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 276 KB

## Abstract The reduction of 3,6‐di‐__tert__‐butyl‐__o__‐benzoquinone with tin amalgam gives the different tin catecholate complexes. The use of polar solvents for this reaction leads to the formation of Cat~2~Sn · L~2~ species (where Cat—dianion of 3,6‐di‐__tert__‐butylcatechol, L = Et~2~O, THF, P