In order to generalize the recently described method for the insolubilization of polysaccharide derivatives to benzoates of cellulose, five mixed 10undecenoate/benzoates of this polysaccharide have been prepared and linked to allyl silica gel by means of a radical reaction. The chiral recognition ab
β¦ LIBER β¦
3,5-Dimethylphenylcarbamates of cellulose and amylose regioselectively bonded to silica gel as chiral stationary phases for high-performance liquid chr
β Scribed by Eiji Yashima; Hiroyasu Fukaya; Yoshio Okamoto
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 753 KB
- Volume
- 677
- Category
- Article
- ISSN
- 1873-3778
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Cellulose tris(3,5dimethylphenylcarbamate) (CDMPC) was coated on largepore silica gels and used as a chiral stationary phase (CSP) for high-performance liquid chromatographic separation of enantiomers. The influences of pore size of silica gel, coating amount of CDMPC, coating solvent, and column te