[3,3]Sigmatropic ring expansion of cycli
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Shinya Harusawa; Shigetaka Takemura; Hirotaka Osaki; Ryuji Yoneda; Takushi Kurih
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Article
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1993
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Elsevier Science
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French
β 770 KB
Yellow scale pheromone 1 has been synthesized via the route illustrated in Scheme 1. The [3,3]sigmatropic ring expansion of I-membered thionocarbonate 4 exclusively produced the Q-lO-membered thiolcarbonate 3, which was transformed via three steps to the intermediate 2 with all the necessary carbon