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3,3,6,6-Tetra­phenyl-trans-tricyclo­[3.1.0.02,4]hexane

✍ Scribed by Clark, George R. ;Tonei, Deborah M. ;Roper, Warren R. ;Wright, L. James

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
124 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

Crystals of (I) were obtained as a very minor by-product of the reaction between Os(CO) 2 (PPh 3 ) 3 and 3,3-diphenylcyclopropene. We have not attempted to develop reproducible reaction conditions.

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4-(Phenylsulfanyl)tricyclo[3.1.0.02,6]hexan-3-one: Synthesis, Alkylation, and Base-Induced Dimerisation
✍ Ulrike Kunz; Stefan Krimm; Thomas Fischer; Thomas Kottke; Dietmar Stalke; Manfre 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 216 KB 👁 1 views

3-(Phenylsulfanyl)benzvalene ( 6) was prepared by de-methyl iodide and 1,3-diiodopropane afforded the alkyl derivatives 9 and 10, respectively, of 7. In the absence of an hydrochlorination from the adduct 5 of phenylsulfenyl chloride to benzvalene (4) with potassium tert-butoxide. An active alkylati