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3,3,11-Trimethyl-7-methylenetricyclo[6.3.0.02,4]undecane-5,11-diol, C15H24O2

✍ Scribed by Crevoisier, M. ;Steudle, K. C. ;Bürgi, H. B.

Book ID
114502204
Publisher
International Union of Crystallography
Year
1984
Tongue
English
Weight
224 KB
Volume
40
Category
Article
ISSN
0108-2701

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📜 SIMILAR VOLUMES

cis-1-Ethyl-4,4,10-trimethyl-2-tosyl-1,2
cis-1-Ethyl-4,4,10-trimethyl-2-tosyl-1,2,3,3a,4,11b-hexahydro-11H-pyrrolo[3,4-c]pyrano[5,6-c]quinolin-11-one
✍ Chinnakali, K. ;Sudha, D. ;Jayagopi, M. ;Raghunathan, R. ;Fun, Hoong-Kun 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 741 KB

The molecule of the title compound, C~26~H~30~N~2~O~4~S, adopts a folded conformation, with the sulfonyl-bound benzene ring lying over the pyridinone ring [centroid-to-centroid distance = 3.893 (1) Å], forming a dihedral angle of 23.87 (5)°. The pyrrolidine ring adopts a twist conformation and the d

trans-1-Ethyl-4,4,10-trimethyl-2-tosyl-1
trans-1-Ethyl-4,4,10-trimethyl-2-tosyl-1,2,3,3a,4,11b-hexahydro-11H-pyrrolo[3,4-c]pyrano[5,6-c]quinolin-11-one
✍ Chinnakali, K. ;Sudha, D. ;Jayagobi, M. ;Raghunathan, R. ;Fun, Hoong-Kun 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 785 KB

The asymmetric unit of the title compound, C 26 H 30 N 2 O 4 S, consists of two independent molecules, A and B, with similar conformations. In both molecules, the pyrrolidine and dihydropyran rings adopt envelope conformations, and are trans-fused; the tosyl group is attached to the pyrrolidine ring