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[3,3]-Sigmatropic Rearrangement/5- exo - dig Cyclization Reactions of Benzyl Alkynyl Ethers: Synthesis of Substituted 2-Indanones and Indenes

✍ Scribed by Tudjarian, Armen A.; Minehan, Thomas G.


Book ID
126004004
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
1012 KB
Volume
76
Category
Article
ISSN
0022-3263

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✍ Kooyeon Lee; Phil Ho Lee 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 115 KB 👁 1 views

## Abstract An efficient method for the annulation of five‐ and six‐membered rings onto α,β‐enones is described __via__ gold‐catalyzed 5‐ and 6‐__exo__‐__dig__ selective cyclizations of alkynyl silyl enol ethers.