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[3,3]-sigmatropic rearrangement of allylic xanthates in β-cyclodextrin complexes

✍ Scribed by Kazunobu Harano; Hideo Kiyonaga; Takuzo Hisano


Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
161 KB
Volume
32
Category
Article
ISSN
0040-4039

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3,3] Sigmatropic rearrangement of allylic alcohols with ethyl P,P-diethoxyacrylate provides a convenient method for the regiospecific synthesis of substituted allylmalonates 2. The [3,3] sigmatropic rearrangement of ally1 vinyl ether derivatives to 7,b-unsaturated carbonyl compounds provides an extr