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[3+3]-Cyclisierungsreaktionen von 1,3-Bis-Silylenolethern mit 1,1-Diacetylcyclopentan und 1,1-Diacetylcyclopropan

✍ Scribed by Peter Langer; Gopal Bose

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
135 KB
Volume
115
Category
Article
ISSN
0044-8249

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[3+3] Cyclizations of 1,3-Bis(silyl enol
[3+3] Cyclizations of 1,3-Bis(silyl enol ether)s with 1,1-Diacetylcyclopentane and 1,1-Diacetylcyclopropane
✍ Peter Langer; Gopal Bose πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 136 KB πŸ‘ 1 views

Domino reactions facilitate the rapid assembly of complex products in a one-pot process. [1] Despite the simplicity of the idea, domino cyclizations of 1,3-dicarbonyl dianions [2] with dielectrophiles are relatively rare. [3] As a result of their high negative charge density, ambident dianions are v