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31P NMR spectroscopic investigation of exchange processes in two bifunctional aminophosphonates

✍ Scribed by R. Boetzel; S. Failla; P. Finocchiaro; G. Hägele


Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
369 KB
Volume
33
Category
Article
ISSN
0749-1581

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✦ Synopsis


Variable-temperature 31P NMR spectroscopy was used to extract Arrhenius and Eyring parameters of the hindered rotation about amide bonds in an acylated aminophosphonate. The results permit the differentiation between stepwise or concerted rotation.