## Abstract 2‐Bromo‐1,5‐di‐t‐butyl‐3‐isopropyl‐benzene was prepared and converted to the 2,4‐di‐t‐butyl‐6‐isopropylphenyl‐substituted phosphonous dichloride, primary phosphine, diphosphenes, and dithioxophosphorane. The ^31^P NMR chemical shifts of these compounds are close to those of 2,4‐di‐t‐but
31P-NMR and SR studies of filled skutterudite compounds (T: Fe, Os)
✍ Scribed by K. Hachitani; H. Fukazawa; Y. Kohori; I. Watanabe; K. Kumagai; C. Sekine; I. Shirotani
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 102 KB
- Volume
- 378-380
- Category
- Article
- ISSN
- 0921-4526
No coin nor oath required. For personal study only.
✦ Synopsis
The 31 P nuclear magnetic resonance ( 31 P-NMR) and muon spin relaxation (mSR) of the filled skutterudite compounds SmT 4 P 12 (T: Fe, Os) have been carried out. From 31 P-NMR, heavy fermion behavior and ferromagnetic spin fluctuations in SmFe 4 P 12 and simple antiferromagnetic spin fluctuations in SmOs 4 P 12 were observed. From mSR, the appearances of static internal magnetic fields below each transition temperature were clarified, which indicates that each ground state is a magnetically ordered state.
📜 SIMILAR VOLUMES
The \*H, '% and 31P NMR data of several Z-R-2-thiono-1,3-dioxa organophosphorus molecules with 7-membered rings [R = 43, OC6H,, C,H,, CH3, N(CH,),] are reported. The conformation of the 7-membered ring is discussed by reference to the 'J(P0CH) coupling constants which are compared with those observe
## Abstract __N__‐Trimethylsilylaminophosphorus compounds containing phosphorus in different oxidation states [P(III) and P(V)] and with different coordination numbers (2, 3 or 4) were studied by ^13^C, ^14^N, ^29^Si and ^31^P NMR, using a variety of one‐ and two‐dimensional (2D) techniques, includ