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31P Differential Line Broadening in the Presence of the59Co Quadrupolar–CSA Interference in Tetrahedral Clusters

✍ Scribed by Pierre Granger; Karim Elbayed; Jésus Raya; Pierre Kempgens; Jacky Rosé


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
191 KB
Volume
117
Category
Article
ISSN
1064-1858

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Differential Line Broadening in the Pres
✍ Karim Elbayed; Pierre Kempgens; Jésus Raya; Pierre Granger; Jacky Rosé 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 256 KB

The formalism for calculating the lineshape of a spin 1/2 J-coupled to a high-spin nucleus undergoing quadrupolar and chemical shift anisotropy (CSA) relaxations is derived in the case where the tensors of both interactions are noncoincident and nonaxial. The expressions show that the CSA-quadrupola