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308. The reductive condensation of 2,5-dimethylpyrrole. A novel isoindoline synthesis

โœ Scribed by Bonnett, R. ;White, J. D.

Book ID
115469953
Publisher
The Royal Society of Chemistry
Year
1963
Weight
703 KB
Category
Article
ISSN
0368-1769

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๐Ÿ“œ SIMILAR VOLUMES

Nitroenamines - 7. Synthesis of 2, 5-bis
Nitroenamines - 7. Synthesis of 2, 5-bis-ฯ‰-aminoalkyl pyrazines through a novel reductive cyclodimerization
โœ S. Rajappa; R. Sreenivasan ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 231 KB

Catalytic reduction of the nitroenamines 1 under neutral conditions to the aminomethyl derivatives ? is well-knowna. We now wish to report the unexpected formation of the symmetrically substituted pyrazines ;! during catalytic reduction of 1 under acidic conditions.