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3-β-d-Ribofuranosyl-6,7-dihydro-9H-thiazolo[3,2-a]purin-9-one hydrate
✍ Scribed by Liaw, Y. C. ;Wang, A. H. J. ;Lin, G. S. ;Chern, J. W.
- Book ID
- 114510790
- Publisher
- International Union of Crystallography
- Year
- 1994
- Tongue
- English
- Weight
- 317 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0108-2701
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The allylic alcohol in ribose-protected zeatin riboside 1, was oxidised to an aldehyde by barium manganate. Heating of the resulting aldehyde in chloroform allowed the cyclizatiin of the N%hain into a 3methylpyrrole ring. After deprotection of the ribose, the title compound was obtained and identifi
An unnatural base pair, 2-amino-6-(N,N-dimethylamino)purine (denoted x) and pyridin-2-one (denoted y), was designed to prove the structural requirements for base pair formation involving shape complementarity. It was expected that y might satisfy the structural requirements for pairing with x, in wh