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3-(Tri­methyl­silyl­ethynyl)­carbazole

✍ Scribed by Khan, Muhammad S. ;Male, Louise ;Raithby, Paul R. ;Teat, Simon J. ;Bond, Andrew D.


Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
198 KB
Volume
59
Category
Article
ISSN
1600-5368

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✦ Synopsis


Single-crystal synchrotron study T = 150 K Mean '(C±C) = 0.005 A Ê R factor = 0.081 wR factor = 0.187 Data-to-parameter ratio = 15.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.


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5,8-Bis­(tri­methyl­silyl­ethynyl)­quino
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Single-crystal X-ray study T = 180 K Mean '(C±C) = 0.006 A Ê R factor = 0.083 wR factor = 0.225 Data-to-parameter ratio = 15.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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In the title compound, C 19 H 30 Si, the double bonds are essentially localized. The central ring and its substituents, including the triple-bond system, are coplanar, with the Si atom lying 0.148 (2) A ˚out of the plane. The packing involves herring-bone layers parallel to the ab plane.

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Single-crystal X-ray study T = 180 K Mean '(C±C) = 0.003 A Ê Disorder in main residue R factor = 0.045 wR factor = 0.110 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.