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3-Rhoda-1,2-dioxolanes through Dioxygenation of a Rhodium–Ethene Complex by Air

✍ Scribed by Monique Krom; Ruud G. E. Coumans; Jan M. M. Smits; Anton W. Gal

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
90 KB
Volume
113
Category
Article
ISSN
0044-8249

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3-Rhoda-1,2-dioxolanes through Dioxygena
3-Rhoda-1,2-dioxolanes through Dioxygenation of a Rhodium–Ethene Complex by Air
✍ Monique Krom; Ruud G. E. Coumans; Jan M. M. Smits; Anton W. Gal 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 90 KB

Proposed as intermediates in the catalytic oxidation of olefins to ketones, 3-rhoda-1,2-dioxolanes (κ C ,O -2-peroxyethyl rhodium complexes) have now been prepared by oxygenation of solid [(N -ligand)Rh (ethene)]PF with air. This process leads to stable isomeric 3-rhoda-1,2-dioxolanes A and B. Upon