The asymmetric unit of the title compound, C~14~H~13~N~3~O~3~·H~2~O, consists of one 4-hydroxy-3-methoxybenzaldehyde nicotinoylhydrazone (NAHZ) molecule and one water molecule linked through hydrogen bonds.
3-Hydroxy-4-methoxybenzaldehyde isonicotinoylhydrazone monohydrate
✍ Scribed by Liu, Hui-Min ;Zhang, Wen-Qin
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 220 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The asymmetric unit of the title compound, C 14 H 13 N 3 O 3 ÁH 2 O, consists of one isonicotinic acid (3-hydroxy-4-methoxybenzylidene)hydrazide (IBH) molecule and one water molecule connected through an O-HÁ Á ÁO hydrogen bond. Further O-HÁ Á ÁO, O-HÁ Á ÁN and N-HÁ Á ÁO hydrogen bonds result in the formation of an intricate three-dimensional supramolecular network.
📜 SIMILAR VOLUMES
The crystal structure of the title compound, C 13 H 12 N 4 O 4 , contains a solvent water molecule which interacts with the organic molecules via intermolecular hydrogen bonds.
The asymmetric unit of the title compound, C~14~H~13~N~3~O~3~·H~2~O, contains one molecule of __N__′-(4-hydroxy-3-methoxybenzylidene)isonicotinohydrazide and one solvent water molecule. The crystal packing is stabilized by O—H...N and O—H...O hydrogen bonds.
In the title compound, C~15~H~15~N~3~O~4~·H~2~O, the organic molecule exists in the keto–imine tautomeric form. The benzene ring makes a dihedral angle of 49.9 (2)° with the pyridine ring. The molecules pack in a three-dimensional framework structure by a combination of O—H...O, O—H...N, N—H...O and